Redox Processes of RutheniumOI ) Polypyridine Complexes Induced by Fast - Atom
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چکیده
Fast-atom bombardment (FAB) mass spectrometry in the negative ionization mode enables the sputtering into the gas phase of the ruthenium complexes [Ru(2,2'-bipyridine[bpY])2(2,5bis(pyrydil)pyrazine[dpp))](PF6)2; [Ru(bpyM2,3-dpp)](PF6)z; [Ru(bpY)z(2,3-dpp-Me)](PF6 ) 3; and [Ru(bPY)i ,u-2,3-dpp)]zRuClz(PF6 )4 as intact radical anions. These data, combined with those available from the positive FAB spectra, allow a full characterization of the analytcs, (J Am Soc Mass Spectrom 1993, 4, 306-311)
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تاریخ انتشار 2001